Isotope effect in dissociative electron attachment to acetylene
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چکیده
منابع مشابه
Dissociative electron attachment to DNA.
Electron-stimulated desorption of anions from thin films of linear and supercoiled DNA is investigated in the range 3-20 eV. Resonant structures are observed with maxima at 9.4+/-0.3, 9.2+/-0.3, and 9.2+/-0.3 eV, respectively, in the yield dependence of H-, O-, and OH- on the incident electron energy. Their formation is attributed to dissociative electron attachment.
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An instrument for the measurement of absolute dissociative electron attachment cross sections was constructed and applied to two prototype molecules, acetylene (C2H2) and deuterated acetylene (C2D2). The isotope effect at the first dissociative electron attachment band at 3 eV was determined--the cross section for C2D-/C2D2 is 14.4 times smaller than that for C2H-/C2H2. The results play a centr...
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ژورنال
عنوان ژورنال: Physical Review A
سال: 2009
ISSN: 1050-2947,1094-1622
DOI: 10.1103/physreva.80.012706